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GHS pictogram GHS07

Exclamation Mark Pictogram (GHS07)

GHS pictogram GHS07: Exclamation Mark

Less severe health hazards: irritation, skin sensitization, harmful acute toxicity, narcotic effects and respiratory tract irritation.

  • GHS07
  • Symbol: Exclamation mark
  • Warning

Hazards this pictogram covers

  • Acute toxicity (harmful, Category 4)
  • Skin irritation
  • Eye irritation
  • Skin sensitization
  • Specific target organ toxicity, single exposure (respiratory irritation, narcotic effects)
  • Hazardous to the ozone layer

Hazard classes and hazard statements

Based on the GHS classification table, GHS07 is assigned to these hazard classes and hazard statements.

Hazard classCategoriesHazard statements
ExplosivesCategory 2CH204
Acute toxicity, oralCategory 4H302
Acute toxicity, dermalCategory 4H312
Skin corrosion/irritationCategory 2H315
Sensitization, SkinCategory 1, 1A, 1BH317
Serious eye damage/eye irritationCategory 2AH319
Acute toxicity, inhalationCategory 4H332
Specific target organ toxicity, single exposure; Respiratory tract irritationCategory 3H335
Specific target organ toxicity, single exposure; Narcotic effectsCategory 3H336
Hazardous to the ozone layerCategory 1H420
Acute toxicity, oral; acute toxicity, dermalCategory 4H302+H312
Acute toxicity, oral; acute toxicity, inhalationCategory 4H302+H332
Acute toxicity, dermal; acute toxicity, inhalationCategory 4H312+H332
Acute toxicity, oral; acute toxicity, dermal; acute toxicity, inhalationCategory 4H302+H312+H332
Skin corrosion/irritation and serious eye damage/eye irritationCategory 2, 2BH315+H320

Typical precautions

These precautionary statements are the ones most often called for by hazards that carry GHS07. The right set for a product depends on its classification.

  • P280: Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...
  • P501: Dispose of contents/container to ...
  • P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
  • P271: Use only outdoors or in a well-ventilated area.
  • P302+P352: IF ON SKIN: wash with plenty of water/...
  • P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
  • P321: Specific treatment (see ... on this label).
  • P362+P364: Take off contaminated clothing and wash it before reuse.

Chemicals carrying GHS07

68 chemicals in our database. Classification comes from each chemical's primary GHS source, so a supplier's SDS may differ.

(+-)-2-Butanol
CAS 78-92-2 · Warning
1-Butanol
CAS 71-36-3 · Danger
1-Decanol
CAS 112-30-1 · Warning
1-Dodecanol
CAS 112-53-8 · Warning
1-Hexanol
CAS 111-27-3 · Warning
1-Nonanol
CAS 143-08-8 · Warning
1-Octanol
CAS 111-87-5 · Warning
1-Pentanol
CAS 71-41-0 · Warning
1-Propanol
CAS 71-23-8 · Danger
1-Tetradecanol
CAS 112-72-1 · Warning
1,1,1-Trichloroethane
CAS 71-55-6 · Warning
1,3-Propanediol
CAS 504-63-2 · Warning
1,4-Butanediol
CAS 110-63-4 · Warning
2-Ethylhexanol
CAS 104-76-7 · Warning
2-Octanol
CAS 123-96-6 · Danger
2-Pentanol
CAS 6032-29-7 · Warning
Acetone
CAS 67-64-1 · Danger
Acetonitrile
CAS 75-05-8 · Danger
Acrylic Acid
CAS 79-10-7 · Danger
Benzene
CAS 71-43-2 · Danger
Benzyl Alcohol
CAS 100-51-6 · Warning
Bisphenol A
CAS 80-05-7 · Danger
Butyl Acetate
CAS 123-86-4 · Warning
Calcium Chloride
CAS 10043-52-4 · Warning
Calcium Hydroxide
CAS 1305-62-0 · Danger
Calcium Oxide
CAS 1305-78-8 · Danger
Cetyl Alcohol
CAS 36653-82-4 · Warning
Chromium Trioxide
CAS 1333-82-0 · Danger
Citric Acid
CAS 77-92-9 · Warning
Copper Sulfate
CAS 7758-98-7 · Warning
Cyclohexane
CAS 110-82-7 · Danger
Cyclohexanol
CAS 108-93-0 · Warning
Diethyl Ether
CAS 60-29-7 · Danger
Diethylene Glycol
CAS 111-46-6 · Warning
Dimethyl Sulfoxide
CAS 67-68-5 · Warning
Dimethylformamide
CAS 68-12-2 · Danger
Diphenylmethane diisocyanate
CAS 101-68-8 · Danger
Dipropylene Glycol
CAS 25265-71-8 · Danger
Ethanolamine
CAS 141-43-5 · Danger
Ethyl Acetate
CAS 141-78-6 · Danger
Ethylene Glycol
CAS 107-21-1 · Warning
Heptane
CAS 142-82-5 · Danger
Heptanol
CAS 111-70-6 · Warning
Hexane
CAS 110-54-3 · Danger
Hydrogen Peroxide
CAS 7722-84-1 · Danger
Isoamyl Alcohol
CAS 123-51-3 · Danger
Isobutanol
CAS 78-83-1 · Danger
Isopropanol
CAS 67-63-0 · Danger
Methyl Ethyl Ketone
CAS 78-93-3 · Danger
Methyl Methacrylate
CAS 80-62-6 · Danger
Naphthalene
CAS 91-20-3 · Warning
Neopentyl glycol
CAS 126-30-7 · Danger
Potassium Hydroxide
CAS 1310-58-3 · Danger
Potassium Permanganate
CAS 7722-64-7 · Danger
Propylene Glycol
CAS 57-55-6 · Danger
Sodium Carbonate
CAS 497-19-8 · Warning
Sodium Cyanide
CAS 143-33-9 · Danger
Sodium Lauryl Sulfate
CAS 151-21-3 · Danger
Stearyl Alcohol
CAS 112-92-5 · Warning
Styrene
CAS 100-42-5 · Danger
tert-Butanol
CAS 75-65-0 · Danger
Tetraethylene Glycol
CAS 112-60-7 · Warning
Tetrahydrofuran
CAS 109-99-9 · Danger
Tetrahydrofurfuryl alcohol
CAS 97-99-4 · Danger
Toluene
CAS 108-88-3 · Danger
Trichloroethylene
CAS 79-01-6 · Danger
Triethanolamine
CAS 102-71-6 · Warning
Triethylene Glycol
CAS 112-27-6 · Warning

GHS07 frequently asked questions

What does the exclamation mark pictogram (GHS07) mean?

Less severe health hazards: irritation, skin sensitization, harmful acute toxicity, narcotic effects and respiratory tract irritation. It is one of the nine GHS hazard pictograms and appears as a black exclamation mark symbol on a white background inside a red diamond border.

Which hazard statements use GHS07?

GHS07 appears with 15 current hazard statements, including H204, H302, H312, H315, H317, H319, H332, H335. The full list is on this page.

What signal word goes with GHS07?

GHS07 is used with the signal word "Warning", depending on the hazard category.

A pictogram shows the type of hazard, not its severity. Read the signal word, hazard statements and the supplier's SDS.

https://pubchem.ncbi.nlm.nih.gov/ghs/ghscode_10.txt (UN GHS Revision 10, retrieved 2026-10-12)